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AUTHOR(S): 

Mihaela Ilie, Florica Marinescu, Gina Ghita, Ana-Maria Anghel, Carmen Tociu, Iustina Popescu, Monica Matei, Holban Elena, György Deák, Marius Raischi, Constantin Cirstinoiu, Uritescu Bogdan

 

TITLE

Spatial Distribution of Heavy Metal Contamination and Ecological Risk Assessment in Water from the Danube River

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ABSTRACT

Heavy metals are considered dangerous contaminants due to the possibility of bioaccumulation and toxic effects on environment and human health. Six metals exhibiting a greater relevance to the aquatic ecosystem in terms of toxic effects (Cd, Cr, Cu, Zn, Ni and Pb) were analyzed from water samples collected monthly from ten sites, during May 2012 - April 2015. The levels of heavy metals in water samples were measured using atomic absorption spectrophotometry (AAS). Results obtained emphasized that the average concentrations of the studied metals from water have decreased as follows: Zn>Cu>Ni>Cr>Pb>Cd. Spatial distribution maps of studied heavy metals were performed using ArcView 9.3 software. Quantifying the risk of aquatic ecosystem exposure to heavy metal pollution was carried out based on ecological hazard quotient (HQ). Exposure to heavy metals in water pose no risk factor.

KEYWORDS

heavy metals, Danube River, ecological risk assessment, toxicity reference values, spatial distribution, statistical analyses

REFERENCES

[1] Comero S., Vaccaro S., Locoro G., Capitani L., Gawlik B.M. Characterization of the Danube River sediments using the PMF multivariate approach. Chemosphere, 95, 2014, pp. 329–335. [1] Comero S., Vaccaro S., Locoro G., Capitani L., Gawlik B.M. Characterization of the Danube River sediments using the PMF multivariate approach. Chemosphere, 95, 2014, pp. 329–335. 

[2] Chitescu L.C., Kaklamanos G., Nicolau I.A., Stolker A.A.M, High sensitive multiresidue analysis of pharmaceuticals and antifungals in surface water using U-HPLC-Q-Exactive Orbitrap HRMS. Application to the Danube river basin on the Romanian territory, Science of the Total Environment, 532, 2015, pp. 501– 511. 

[3] Ilie M., F. Marinescu M., Szep R., Ghita G., Deák Gy., Anghel A.M., Petrescu A., Uritescu B., Ecological risk assessment of heavy metals in surface sediments from the Danube river, Carpathian Journal of Earth and Environmental Sciences, 12, 2, 2017, pp. 437- 445. 

[4] Dauvalter V., Rognerud S. Heavy metal pollution in sediments of the Pasvik River drainage. Chemosphere, 42, 2001, pp. 9–18. 

[5] Gaur V.K., Gupta S.K., Pandey S.D., Gopal K., Misra V. Distribution of heavy metals in sediment and water of River Gomti. Environmental Monitoring and Assessment, 102, 2005, pp. 419–433. 

[6] Koś K., EUGENIUSZ Zawisza E. Heavy metals contamination of sediments from chosen dam reservoirs in terms of their usage in earthworks. WSEAS Transactions on Environment and Development, 11, 2015, pp. 136-142. 

[7] Carr G.M., Neary J.P., Water Quality for Ecosystem and Human Health, 2nd Edition, United Nations Environment Programme Global Environment Monitoring System/Water Programme, 2008. 

[8] Marinescu F., Tociu C., Ilie M., Anghel A.M. The influence of toxic pollutants on the absolute value and on the kinetics of the degradation of organic substances quantified as BOD, Bionterface Research in Applied Chemistry, 2017. 

[9] Anghel A.M., Ilie M., Ghita G., Marinescu F., Deák Gy., Assessing the Aquatic Environment Quality Contaminated with Heavy Metals as a Result of Polymetallic Mining in the NorthWest Region of Romania Using Pollution Indices, International Journal of Environmental Science and Development, 8(2), 2017, p.p. 111-115, doi: 10.18178/ijesd.2017.8.2.931. 

[10] Daescu A. I., Holban E., Boboc M. G., Raischi M. C., Matei M., Ilie M., Deák Gy., Performant technology to remove organic and inorganic pollutants from wastewaters, Journal of Environmental Protection and Ecology, 2017. 

[11] Wang L.F., Yang L.Y., Kong L.H., Li S., Zhu J.R., Wang Y.Q., 2014. Spatial distribution, source identification and pollution assessment of metal content in the surface sediments of Nansi Lake, China. Journal of Geochemical Exploration, 140, 2014, pp.87-95. 

[12] Suter G.W.II, Efroymson R.A., Sample B.E., Jones D.S. Ecological Risk Assessment for Contaminated Sites, Lewis Publishers, Boca Raton, Florida, USA., 2000. 

[13] Maria C., Tociu C., Maria G. Improvement of Aquatic Pollutant Partition Coefficient Correlations Using 1D Molecular Descriptors – Chlorobenzene Case Study, Chemical Papers, 67, 2013, pp. 173-185. 

[14] Raischi M. C., Oprea L., Deák Gy., Zamfir S., Ilie M., Raischi N., Impact of the Lower Danube hydro technical works on sturgeons’ migration. International Journal of Environmental Science, Volume 1, 2016, pp. 213-219. 

[15] USEPA. Guidelines for Ecological Risk Assessment Final. Risk Assessment Forum. U.S. Environmental Protection Agency, 1998. 

[16] Anghel A.M, Diacu E., Ilie M., Petrescu A., Ghita G., Marinescu F., Deák Gy., Statistical analysis of heavy metals concentration in water and sediments in the lower part of the Danube River – Romanian section, Rev. Chim. (Bucharest), 67, 11, 2016, pp. 2151-2155. 

[17] Sakan S., Grñeti I., Dordevic D. Distribution and Fractionation of Heavy Metals in the Tisa (Tisza) River Sediments. Environmental Science and Pollution Research, 14 (4), 2007, pp. 229-236. 

[18] Slobodanka Pajević S., Borišev M., Rončević S., Vukov D., Igić R. Heavy metal accumulation of Danube river aquatic plants – indication of chemical contamination. Central European Journal of Biology, 3(3), 2008, pp. 285–294. 

[19] Ren J., Shang Z., Tao L., Wang X. Multivariate analysis and heavy metals pollution evaluation in Yellow River surface sediments. Polish Journal of Environmental Studies, 24 (3), 2015 pp. 1041-1048. 

[20] Liu R., Men C., Liu Y., Yu W., Xu F., Shen Z. Spatial distribution and pollution evaluation of heavy metals in Yangtze estuary sediment. Marine Pollution Bulletin, 110, 2016, pp. 564- 571. 

[21] Environment Canada. Priority substances list assessment report: nickel and its compounds. Canadian Environmental Protection Act. National Printers (Ottawa) Inc., 1994. 

[22] Horne M.T. and Dunson W.A. Effects of low pH, metals, and water hardness on larval amphibians. Archives of Environmental Contamination and Toxicology. 29, 1995, pp 500-505. 

[23] ***Order of the Ministry of Environmental and Water No 161/2006 for the Approval of the Norm Concerning the Reference Objectives for the Surface Water Quality Classification (including Quality Standards for Sediments). Official Monitor of Romania, Part 1, No 511 bis. 

[24] ***WFD, 2000. Directive 2000/60/EC of the European Parliament and of the Council of 23 October 2000 Establishing a Framework for Community Action in the Field of Water Policy. 

[25] ***Joint Danube Survey 3 Final Report. ICPDR, 2015. 

[26] Cui S., Fu Q., Li T., Ma W., Liu D., Wang M. Sediment-Water exchange, spatial variations, and ecological risk assessment of Polycyclic Aromatic Hydrocarbons (PAHs) in the Songhua River, China. Water, 8(8), 2016, pp. 334-346. 

[27] USEPA. Toxicity Reference Values. Screening Level Ecological Risk Assessment Protocol. Appendix E., 1999. 

[28] Soliman N.F., Nasr S.M., Okbah M.A. Potential ecological risk of heavy metals in sediments from the Mediterranean coast, Egypt. Journal of Environmental Health Science & Engineering, 13(1), 2015, pp.70-81. 

[29] Simpson S.L., Batley G.E., Chariton A.A., Stauber J.L., King C.K., Chapman J.C., Hyne R.V., Gale S.A., Roach A.C., Maher W.A. Handbook for sediment quality assessment. Bangor: CSIRO; 2005.

Cite this paper

Mihaela Ilie, Florica Marinescu, Gina Ghita, Ana-Maria Anghel, Carmen Tociu, Iustina Popescu, Monica Matei, Holban Elena, György Deák, Marius Raischi, Constantin Cirstinoiu, Uritescu Bogdan. (2017) Spatial Distribution of Heavy Metal Contamination and Ecological Risk Assessment in Water from the Danube River. International Journal of Environmental Science, 2, 118-1124

 

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