oalogo2  

AUTHOR(S): 

Vincenzo Piemonte, Mauro Capocelli, Marina Prisciandaro

 

TITLE

Kinetic Features of PCDD Adsorption in Carbon Beds

pdf PDF

ABSTRACT

In this paper, starting from the knowledge of thermodynamic parameters, the adsorption of toxic dioxins is studied in the conditions typically encountered in flue gas treatment processes. The six more poisonous species among all congeners of dioxin group are considered. In particular the theoretical adsorption isotherms are derived and a mathematical tool for planning a feasible fixed bed adsorbers proposed, based on breakthrough and the mass transfer zone curves.

KEYWORDS

Dioxin, adsorption, activated carbon. kinetics modelling, breakthrough curves, mass transfer zone curves

REFERENCES

[1] Viel, J.F., Arveux, P., Baverel, J., Cahn, J.Y., “Soft-tissue sarcoma and non-Hodgkin’s lymphoma clusters around a municipal solid waste incinerator with high dioxin emission levels”, Am. J.Epidem. (2000), 152, 13-19. [1] Viel, J.F., Arveux, P., Baverel, J., Cahn, J.Y., “Soft-tissue sarcoma and non-Hodgkin’s lymphoma clusters around a municipal solid waste incinerator with high dioxin emission levels”, Am. J.Epidem. (2000), 152, 13-19. 

[2] Chopra, M. and D. Schrenk, Dioxin toxicity, aryl hydrocarbon receptor signaling, and apoptosis—Persistent pollutants affect programmed cell death. Critical Reviews in Toxicology, 2011. 41(4): p. 292-320. 

[3] Hooth, M.J., et al., Repeated dose toxicity and relative potency of 1,2,3,4,6,7- hexachloronaphthalene (PCN 66) 1,2,3,5,6,7- hexachloronaphthalene (PCN 67) compared to 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) for induction of CYP1A1, CYP1A2 and thymic atrophy in female Harlan Sprague–Dawley rats. Toxicology, 2012. 301(1–3): p. 85-93. 

[4] Ishikawa, R., Buekens, A., Huang, H., Watanabe, K., “Influence of combustion conditions on dioxin in an industrial scale fluidized-bed incinerator: experimental study and statistical modelling”, Chemosphere (1997), 35, 465-477. 

[5] Reichelt, J., et al., Formation of deposits on the surfaces of superheaters and economisers of MSW incinerator plants. Waste Management, 2013. 33 (1): p. 43-51. 

[6] Aurell, J., J. Fick, and S. Marklund, Effects of Transient Combustion Conditions on the Formation of Polychlorinated Dibenzo-pDioxins, Dibenzofurans, and Benzenes, and Polycyclic Aromatic Hydrocarbons During Municipal Solid Waste Incineration. Environmental Engineering Science, 2009. 26(3): p. 509-520. 

[7] McKay, G., Dioxin characterisation, formation and minimisation during municipal solid waste (MSW) incineration: review. Chemical Engineering Journal, 2002. 86(3): p. 343-368. 

[8] Aurell, J., S. Jansson, and S. Marklund, Effects of Quench Time Profiles on PCDD/F Formation in the Postcombustion Zone during Municipal Solid Waste Incineration. Environmental Engineering Science, 2009. 26(3): p. 541-550. 

[9] Jansson, S., L. Lundin, and R. Grabic, Characterisation and fingerprinting of PCBs in flue gas and ash from waste incineration and in technical mixtures. Chemosphere, 2011. 85(3): p. 509-515. 

[10] Van Caneghem, J., C. Block, and C. Vandecasteele, Destruction and formation of dioxin-like PCBs in dedicated full scale waste incinerators. Chemosphere, 2014. 94(0): p. 42- 47. 

[11] Phan, D.N.C., S. Jansson, and J.-F. Boily, Link between Fly Ash Properties and Polychlorinated Organic Pollutants Formed during Simulated Municipal Solid Waste Incineration. Energy & Fuels, 2014. 28(4): p. 2761-2769. 

[12] Prisciandaro M.,Ronconi S.,Capocelli M., Piemonte V., Thermodynamic features of PCDD adsorption, submitted to Journal of Hazardous Materials. 

[13] Aris, R., Amudson, N. R., Mathematical Methods in Chemical Engineering (1973), Prentice-Hall, Englewood Cliffs. 

[14] Karatza, D., Lancia, A., Musmarra, D. “Fly ash capture of mercuric chloride vapors from exhaust combustion gas”, Env. Sci. Technol. (1998), 32, 3999-4004. 

[15] Thomas, (1947) (as cited by Aris, R. , Amudson, N. R., Mathematical Methods in Chemical Engineering, Prentice-Hall, Englewood Cliffs (1973)) 

[16] EPA, Carbon Adsorbers, 1995. 

[17] Atkins,P.W., Chimica fisica, (1982), Zanichelli.

Cite this paper

Vincenzo Piemonte, Mauro Capocelli, Marina Prisciandaro. (2016) Kinetic Features of PCDD Adsorption in Carbon Beds. Environmental Science, 1, 195-199

 

cc.png
Copyright © 2016 Author(s) retain the copyright of this article.
This article is published under the terms of the Creative Commons Attribution License 4.0